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Grade 10 Science · Unit 3: Bonding, acids and reactivity

The reactivity series and extracting metals

Use the reactivity series, displacement and redox to explain how metals are extracted.

The reactivity series lists metals from most to least reactive: potassium, sodium, lithium, calcium, magnesium, (carbon), zinc, iron, (hydrogen), copper, silver, gold. More reactive metals lose electrons more easily to form positive ions. A more reactive metal displaces a less reactive metal from a solution of its compound: iron + copper sulfate → iron sulfate + copper.

Oxidation is the gain of oxygen or the loss of electrons; reduction is the loss of oxygen or the gain of electrons (OIL RIG). Gold and silver are found as the metals themselves because they are unreactive. Metals less reactive than carbon, such as iron and zinc, are extracted by heating their oxides with carbon, which reduces them. Metals more reactive than carbon, such as aluminium, must be extracted by electrolysis, which uses much more energy.

Worked example

Will zinc displace copper from copper sulfate solution?

  1. Zinc is above copper in the reactivity series.
  2. A more reactive metal displaces a less reactive one.

Answer:Yes: zinc + copper sulfate → zinc sulfate + copper.

Key words

reactivity series
metals in order of reactivity
displacement
a more reactive metal takes the place of a less reactive one
oxidation
gain of oxygen or loss of electrons
reduction
loss of oxygen or gain of electrons
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NGSS-referenced: HS-PS1-2